Product ID:PUR-FECT TOOL I RESIN
MSDS Date:11/09/1989
FSC:8030
NIIN:01-229-2659
Kit Part:Y
MSDS Number: BKJVR

CIBA-GEIGY CORPORATION FORMULATED SYSTEMS GROUP

4917 DAWN AVE.
EAST LANSING, MI 48823
US

Emergency Phone: 800-888-8372

Info Phone: 517-351-5900

Preparer: PETER HENIGE

Cage: CIBAG

CIBA-GEIGY CORPORATION, FURANE PRODUCTS

LOS ANGELES, CA 90039 US

Telephone: 818-247-6210

Cage: CIBAG

METHYLENE BISPHENYL ISOCYANATE (MDI) (SARA III)

CAS: 101-68-8

RTECS: NQ9350000

OSHA PEL C, 0.02 PPM

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

BARIUM SULFATE

CAS: 7727-43-7

RTECS: CR0600000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

POLYMETHYLENE POLYPHENYL ISOCYANATE (POLYMERIC MDI)

CAS: 9016-87-9

RTECS: TR0350000

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

GLASS, OXIDE

CAS: 65997-17-3

OSHA PEL 5 MG/M3 RESP

ACGIH TLV: 10 MG/M3 AIR TDUST

SOLVENT NAPHTA,(PETROLEUM) HEAVY AROMATIC

CAS: 64742-94-5

RTECS: SE7546500

Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES ALLERGIC SKIN AND RESPIRATORY
REACTIONS LEADING TO ASTHMA TYPE SPASMS OF THE BRONCHIAL TUBES AND
DIFFICULTY IN BREATHING.
Effects of Overexposure:CONTACT WITH LIQUID CAUSES EYE AND SKIN
IRRITATION. IF INHALED CAUSES BREATHLESSNESS, CHEST DISCOMFORT AND
REDUCED PULMONARY FUNCTION. MAY CAUSE ALLERGIC SKIN AND RESPIRATORY
REACTIONS IN SOME INDIVID UALS, LEADING TO ASTHMA TYPE SPASMS OF
THE BRONCHIAL TUBES AND DIFFICULTY IN BREATHING.
Medical Cond Aggravated by Exposure:PERSONS WITH ASTHMATIC-TYPE
CONDITIONS,CHRONIC BRONCHITIS,OTHER CHRONIC RESPIRATORY DISEASES,
EYE CONDITIONS OR RECURRENT SKIN ECZEMA OR SENSITIZATION SHOULD BE
EXCLUDED FROM WORKING WITH ISOCYANATES.

First Aid:EYES:IMMEDIATELY FLUSH WITH WATER FOR 15 MIN.CALL A
DOCTOR.SKIN:WASH WITH SOAP & WATER.REMOVE CONTAMINATED CLOTHING &
LAUNDER BEFORE RE-USE.INGESTION:IF CONSCIOUS,GIVE PLENTY OF WATER
TO DRINK.DO NOT INDUCE VOMITING.CALL A PHYSICIAN.INHALATION:REMOVE
TO FRESH AIR.GIVE OXYGEN AND/OR ARTIFICIAL RESPIRATION,IF
NEEDED.CALL A DOCTOR.OTHER:REFERRAL TO A DOCTOR IS RECOMMENDED IF
THERE ARE QUESTIONS.

Flash Point:>200F,>93C
Extinguishing Media:CARBON DIOXIDE, FOAM, OR WATER.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY
BE TOXIC. AVOID WATER CONTAMINATION IN CLOSED CONTAINERS OR
CONFINED SPACES. CARBON DIOXIDE EVOLVED.

Spill Release Procedures:ABSORB WITH ABSORBENT MATERIAL AND PLACE IN
OPEN TOP CONTAINER. UNDER GOOD VENTILATION, DECONTAMINATE ABSORBENT
AND SPILL AREA WITH A MIXTURE OF 90% WATER, 8% AMMONIA AND 2%
DETERGENT. LEAVE VENTILATE D 24 HOURS BEFORE DISPOSAL. AVOID
CONTACT.

Handling and Storage Precautions:WARNING!HARMFUL IF INHALED,CAUSES SKIN
AND EYE IRRITATION. CAUSES ALLERGIC SKIN AND RESPIRATORY REACTION.
AVOID CONTACT WITH EYES, SKIN, AND CLOTHING.
Other Precautions:AVOID BREATHING VAPOR OR MIST. AVOID PROLONGED OR
REPEATED CONTACT WITH SKIN. KEEP CONTAINER CLOSED. USE WITH
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:ORGANIC VAPOR RESPIRATOR IF TLV IS NOT EXCEEDED.
FOR EXPOSURES IN EXCESS OF THE TLV, AN AIR SUPPLIED RESPIRATOR
WOULD BE REQUIRED.
Ventilation:GENERAL MECHANICAL AND LOCAL EXHAUST IN ACCORDANCE WITH
ACGIH RECOMMENDATIONS.
Protective Gloves:IMPERVIOUS SYNTHETIC GLOVES.
Eye Protection:WEAR SPLASH-PROOF CHEMICAL GOGGLES.
Supplemental Safety and Health

Vapor Density:>1
Spec Gravity:1.86
Solubility in Water:REACTS WITH WATER
Appearance and Odor:WHITE FILLED LIQUID WITH AROMATIC ODOR
Percent Volatiles by Volume:NEG

Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS, STRONG OXIDIZING AGENTS, STRONG BASES, METAL-ORGANIC
COMPOUNDS.
Stability Condition to Avoid:AVOID PROLONGED HEATING OVER 160F OR
STORING BELOW 75F. AVOID WATER CONTAMINATION.
Hazardous Decomposition Products:COMBUSTION MAY FORM TOXIC MATERIALS.
CO, C02, BENZENE, TOLUENE, OXIDES OF NITROGEN, HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:CONTAMINATION WITH MOISTURE AND
OTHER PRODUCTS THAT REACT WITH ISOCYANATES.

Waste Disposal Methods:CONSULT QUALIFIED LOCAL OR CORPORATE PERSONNEL
FOR METHOD THAT WILL COMPLY WITH LOCAL, STATE AND FEDERAL HEALTH
AND ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.